WebNov 20, 2024 · DOI: 10.1039/C7CE01766A Corpus ID: 103853697; Separation of C2/C1 hydrocarbons through a gate-opening effect in a microporous metal–organic framework @article{Lin2024SeparationOC, title={Separation of C2/C1 hydrocarbons through a gate-opening effect in a microporous metal–organic framework}, author={Rong-Guang Lin … WebApr 27, 2024 · The in situ gas sorption PXRD experiment verifies that the gate-opening effect takes place in the atmospheric environment of CO 2 but not for N 2 or CH 4. …
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WebApr 2, 2024 · Interestingly, a shape memory effect is observed for Cu(4-PyC) 2 during the second SO 2 sorption cycle. When comparing the different gate-opening pressures of each gas, we observed that the structural flexibility of the three frameworks is highly sensitive to the chemical hardness of the Lewis acidic metal ions (Mg 2+ > Mn 2+ > Cu 2+). WebFeb 23, 2016 · The gate-opening phenomenon in ZIFs is of paramount importance to understand their behavior in industrial molecular separations. Here we show for the first time using in situ inelastic neutron scattering … emil altmeyer gmbh bochum
Tuning the Structural Flexibility for Multi-Responsive Gas Sorption …
WebAug 15, 2024 · No gate-opening effect was observed for C 3 H 8 at the temperature from 273 to 298 K. Clearly, CPL-1 can realize the C 3 H 6 /C 3 H 8 separation through the … WebSep 16, 2024 · The gate-opening effect was considered in terms of six-membered ring window diameter distributions. When the numbers of CO 2 2 molecules but also temperatures can induce the gate-opening effect. References. Morris W et al (2008) Crystals as molecules: postsynthesis covalent functionalization of zeolitic imidazolate … WebJun 1, 2024 · Efficient One-Step Purification of C 1 and C 2 Hydrocarbons over CO 2 in a New CO 2-Selective MOF with a Gate-Opening Effect Li-Na Ma Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, … emiko\\u0027s cat often meows for food